In terms of the air temperature and water vapor content, explain how the relative humidity normally changes during the course of a 24-hour day

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ANSWER: Student answers may vary slightly, but need to demonstrate comprehension of the following concepts. An increase in the water vapor content of the air (with no change in air temperature) increases the air's relative humidity. The reason for this increase resides in the fact that, as more water vapor molecules are added to the air, there is a greater likelihood that some of the vapor molecules will stick together and condense. Condensation takes place in saturated air. Therefore, as more and more water vapor molecules are added to the air, the air gradually approaches saturation, and the relative humidity of the air increases. Conversely, removing water vapor from the air decreases the likelihood of saturation, which lowers the air's relative humidity. In summary, with no change in air temperature, adding water vapor to the air increases the relative humidity; removing water vapor from the air lowers the relative humidity.
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As the air temperature increases (with no change in water vapor content), the relative humidity decreases. This decrease in relative humidity occurs because in the warmer air the water vapor molecules are zipping about at such high speeds they are unlikely to join together and condense. The higher the temperature, the faster the molecular speed, the less likely saturation will occur, and the lower the relative humidity. As the air temperature lowers, the water vapor molecules move more slowly, condensation becomes more likely as the air approaches saturation, and the relative humidity increases. In summary, with no change in water vapor content, an increase in air temperature lowers the relative humidity, while a decrease in air temperature raises the relative humidity.
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In many places, the air's total vapor content varies only slightly during an entire day, so it is the changing air temperature that primarily regulates daily variations in relative humidity. As the air cools at night, the relative humidity increases. Normally, the highest relative humidity occurs in the early morning, during the coolest part of the day. As the air warms during the day, the relative humidity decreases, with the lowest values generally occurring during the warmest part of the afternoon.

Environmental & Atmospheric Sciences

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