Which of the following is not an assumption used for the van Laar model with the Scatchard-Hildebrand defined parameters?

A. The system excess molar volume is zero.
B. The enthalpy of vaporization of the components in the system are equal to the internal energy of vaporization.
C. The system excess molar entropy is zero.
D. None of the above are assumptions.
E. All of the above are assumptions.


A. Incorrect. This is one of the two definitions of regular solution theory.
B. Correct. While the internal energy of vaporization is required to calculate the solubility parameters, it is often assumed to equal the enthalpy of vaporization minus RT.
C. Incorrect. This is one of the two definitions of regular solution theory.
D. Incorrect. At least one is an assumption.
E. Incorrect. At least one is not an assumption.

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