One kilogram of air is heated reversibly at constant pressure from an initial state of 300 K and 1 bar until its volume triples. Calculate W, Q, ?U, and ?H for the process. Assume for air that PV / T = and

What will be an ideal response?


If PV/T is constant then at constant pressure, the volume will triple when the temperature triples, so the final state will be 900 K and 1 bar. The enthalpy change for this constant volume process with constant heat capacity is given by

where we've used the molecular weight of air of about

to convert from molar enthalpy change to specific enthalpy change.

By the definition of U, we have



The work is given by –P?V = –?PV at constant P, which we just computed to be

. For a constant pressure process, Q is equal to the enthalpy change, so Q = 600 kJ/kg

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