For an atom of hydrogen without the effects of an external magnetic field, an electron transition from the 3P subshell to the 2P subshell is called a forbidden transition. Why is this so?
d.
A photon must be emitted when the electron transitions from n = 3 to n = 2, and the photon carries a specific angular momentum of l = ±1. The transition from a P subshell to another Psubshell, both with angular momentum l = 2, is therefore forbidden.
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