The conditions of a gas change in a steady-flow process from 20°C and 1000 kPa to 60°C and 100 kPa. Devise a reversible nonflow process (any number of steps) for accomplishing this change of state, and calculate ?U and ?H for the process on the basis of 1 mol of gas. Assume for the gas that PV/T is constant, and

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This is a two-step process, going first from 20°C to 60°C, and then 1000 kPa to 100 kPa. So for temperature: = 293.16 K and = 333.16 k , and using to determine the intermediate temperature and the volume changes we have



Using the intermediate temperature to determine the temperature change in both steps we have

= ?263.844 k and = 303.844 k.

Using =, and plugging the temperatures into we have for Step A:



And for Step B:



Now using these to determine the total ?U and ?H

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