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The decomposition of nitrogen dioxide into nitrogen monoxide and oxygen is a second-order reaction. This means that the concentration C of at time t is given by 1/C=kt+1/, where is the initial concentration and k is the rate constant. Assume the initial concentration is known to be 0.03 mol/L exactly. Assume that time can be measured with negligible uncertainty.

a. After 40 s, the concentration C is measured to be 0.0023 ± 2.0 ×10–4mol/L. Estimate the rate constant k, and find the uncertainty in the estimate.
b. After 50 s, the concentration C is measured to be 0.0018 ± 2.0 ×10–4mol/L. Estimate the rate constant k, and find the uncertainty in the estimate.
c. Denote the estimates of the rate constant k in parts (a) and (b) by , respectively. The average is used as an estimate of k. Find the uncertainty in this estimate.
d. Find the value of c so that the weighted average has the smallest uncertainty.


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Technician A says that distilled or clean drinking water should be added to a battery when the electrolyte level is low. Technician B says that fresh electrolyte (solution of acid and water) should be added. Which technician is correct?

A) Technician A only B) Technician B only C) Both technicians A and B D) Neither technician A nor B

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What is the most common size (width and length) of sheet paneling?

A) 4' × 9' B) 4' × 8' C) 4' × 12' D) 4' × 16'

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In modern GM engines, what type of sensor is the throttle position sensor (TPS)?

A. Thermistor B. Hall effect sensors C. Rheostat D. Potentiometer

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